Barium sulphate is insoluble.



(i) Name two solutions which you could mix to give a precipitate of barium sulphate.

(ii) Describe what you would do to obtain barium sulphate from the mixture.

(iii) Write a balanced equation for the reaction. State symbols are required.

(iv) Formulate the ionic equation.

(v) Identify the precipitate in the net ionic equation.

Verified Answer :

  • The reagents used for this precipitation are Barium Chloride and Sodium Sulphate.
  • To obtain the precipitate, filter the reaction mixture to isolate the solid Barium Sulphate.
  • The balanced equation is \(BaCl_2 (aq) + Na_2SO_4 (aq) \rightarrow BaSO_4 (s) + 2NaCl (aq)\).
  • The net ionic equation is \(Ba^{2+} (aq) + SO_4^{2-} (aq) \rightarrow BaSO_4 (s)\), and the precipitate is \(\boxed{BaSO_4}\).

Explanation

  1. Analysis of the Precipitation Reaction

We are analyzing the chemical precipitation reaction used to produce barium sulphate. The objective is to identify the reagents, the procedure, and the balanced and ionic equations associated with the formation of this insoluble salt. Precipitates are solids formed during a chemical reaction between substances in aqueous solutions.

  1. Selection of Reagents

To obtain a precipitate of barium sulphate (\(BaSO_4\)), we react a solution containing barium ions with a solution containing sulphate ions. A suitable combination of reagents is Barium Chloride (\(BaCl_2\)) and Sodium Sulphate (\(Na_2SO_4\)). Both are soluble in water.

  1. Obtaining the Precipitate

To isolate the insoluble barium sulphate precipitate from the aqueous mixture of products, one should use the technique of filtration. After mixing the two solutions, the solid barium sulphate is captured on filter paper, while the sodium chloride remains in the filtrate (the liquid that passes through the paper). The precipitate on the paper can then be washed with distilled water and dried to obtain pure barium sulphate.

  1. Balanced Chemical Equation

The balanced chemical equation for the reaction is:
\[BaCl_2 (aq) + Na_2SO_4 (aq) \rightarrow BaSO_4 (s) + 2NaCl (aq)\]
In this reaction, the barium ions (\(Ba^{2+}\)) and sulphate ions (\(SO_4^{2-}\)) combine to form the insoluble solid, denoted by the state symbol (s).

  1. Net Ionic Equation and Identification of the Precipitate

The net ionic equation isolates the species that actively participate in the formation of the precipitate:
\[Ba^{2+} (aq) + SO_4^{2-} (aq) \rightarrow BaSO_4 (s)\]
The precipitate is the solid substance formed in the reaction, which is Barium Sulphate (\(BaSO_4\)).

Examples

In real-world applications, precipitation is a vital method for separating substances. For example, water treatment plants often use precipitation to remove heavy metals from wastewater, and in analytical chemistry, it is used to detect the presence of specific ions in unknown samples. By understanding how to create and separate a precipitate, we gain control over chemical purification processes, ensuring clean water and accurate laboratory results.