Using the conversion factor from eV (electron volts) to joules, determine which energy line for an electron dropping from one energy level to another would show a line at 435 nm in an emission spectrum. Use the formulas and the energy level information below to answer the question.

Needed constants:


1.00eV = 1.6 10^-19 J

c = 3.00
10^8 m/s

h = 6.63 10^-34 Js


Energy Level Values:

E6: E= -0.378 eV

E5: E= -0.544 eV

E4: E= -0.850 eV

E3: E= -1.51 eV

E2: E= -3.403V

Verified Answer :

The formula used to solve this is:
E = hc/λ

The given values can then be subsituted into the equation to sovle for the energy:

E = (6.63 x 10^-34 J-s) (3 x 10^8 m/s) / 435 x10^-9 m
E = 4.5724 x 10^-19 J

converting to electron volts
E = 4.5724 x 10^-19 J  1.00eV / 1.6 10^-19 J
E = 2.86 eV

The closest energy line is
E2

Explanation:

Wavelength in an emission spectrum,  \(\lambda=435\ nm=435\times 10^{-9}\ m\)  

The energy of an electron is given by :

\(E=\dfrac{hc}{\lambda}\)

Where

h is the Planck's constant

c is the speed of light

For 435 nm, the energy of the electron will be :

\(E=\dfrac{6.63\times 10^{-34}\times 3\times 10^8\ m/s}{435\times 10^{-9}}\)

\(E=4.57\times 10^{-19}\ J\)

We know that \(1\ eV=1.6\times 10^{-19}\ J\)

So, \(E=\dfrac{4.57\times 10^{-19}}{1.6\times 10^{-19}}\)

So, E = 2.86 eV

The energy of the electron dropping from one energy level is 2.86 eV. We know that,

\(\dfrac{hc}{\lambda}=E_{n_2}-E_{n_1}\)

From the given energy levels :

\(E_5-E_2=-0.544-(-3.403)\)

\(E_5-E_2=2.859\ eV\)

So, the transition must be from E₅ to E₂. Hence, this is the required solution.