Calculate the approximate enthalpy change, ΔHrxn, for the combustion of methane:

CH4+2O2→2H2O+CO2


ΔHrxn from a given table:

CH4 = 1656 kJ/mol

O2 = 498 kJ/mol

H2O = 928 kJ/mol

CO2 = 1598 kJ/mol

ΔHrxn = [(1656) + (2498)] - [(2928) + (1598)] = -802 kJ/mol ?

Verified Answer :

The heat of combustion is obtained by getting the difference between the summation of enthalpies of the products and the enthalpies of the reactants. Hence the equation is enthalpy change= 1598 kJ+2*928 kJ-1656 kJ-498 kJ. The answer is 1300 kJ.

We subtract the enthalpies of the products by the enthalpies of the reactants, taking into account their stoichiometric coefficients:
2ΔH(H2O) + ΔH(CO2) - ΔH(CH4) - ΔH(2O2)= 2(928) + 1598 - 1656 - 2(498)= 802 kJ / 1 mol methane