A researcher studying the nutritional value of a new candy places a 4.40-gram sample of the candy inside a bomb calorimeter and combusts it in excess oxygen. The observed temperature increase is 2.87 °C. If the heat capacity of the calorimeter is 41.50 kJ·K–1, how many nutritional Calories are there per gram of the candy?
Calories = 1gCandy (41.50KJ / 4.40gCandy) (239calories / 1KJ)
q = (41.50 KJ / K) (276.02 K)
q = 11454.83 KJ
Calories = 1gCandy (11454.83 KJ / 4.40gCandy) * (1 KCal / 4.184 KJ)
Calories = 622 KCal
Answer:
Nutritional calories per gram of candy = \(\frac{2.74\times 10^{3}}{4.40}cal/g=6.23\times 10^{2} nutritional cal/g\)
Explanation:
Total amount of heat released due to combustion of the candy = (\(C_{cal}\times \Delta T\))
where \(C_{cal}\) is the heat capacity of calorimeter and \(\Delta T\) is the increase in temperature.
Here, \(C_{cal}\) = 41.50 kJ/K and \(\Delta T\) = (273+2.87) K = 275.87 K
So, Total amount of heat released due to combustion of the candy = \((41.50\times 275.87)kJ=11449 kJ\)
Now, 1 kJ = 0.239 nutritional cal
So, 11449 kJ = \((0.239\times 11449)cal=2.74\times 10^{3}cal\)
hence nutritional calories per gram of candy = \(\frac{2.74\times 10^{3}}{4.40}cal/g=6.23\times 10^{2} nutritional cal/g\)