Verified Answer :

Real gases deviate from ideal gases when there
are conditions such as low temperature and high pressures. Charles' law holds
the pressure constant with varying temperature. Given that there is constant
pressure, low temperatures cause the deviation from the state of ideality. 

Answer:

high pressures and temperatures close to liquefaction.

Explanation:

Actually, like Boyle's Law, Charles's Law represents behavior of an ideal gas. For any real gas, deviations are observed at high pressures and temperatures close to liquefaction.