The atomic radius of metal X is 1.20 × 102 picometers (pm) and a crystal of metal X has a unit cell that is face-centered cubic. Calculate the density of metal X?(atomic weight = 42.3 g/mol)

Verified Answer :

The formula for density is density = \(\frac{number of atoms in FCC * atomic weight}{ radius^{3}*Na}\). Substituting the given, the density is 162.69 g/cm3.

Answer: The density of metal X is \(7.19g/cm^3\)

Explanation:

We are given:

Atomic radius of metal X = \(1.20\times 10^2pm=120pm\)

To calculate the edge length, we use the relation between the radius and edge length for FCC lattice:

\(a=2\sqrt{2}R\)

Putting values in above equation, we get:

\(a=2\sqrt{2}\times 20=339.4pm\)

To calculate the density of metal, we use the equation:

\(\rho=\frac{Z\times M}{N_{A}\times a^{3}}\)

where,

\(\rho\) = density

Z = number of atom in unit cell = 4  (FCC)

M = atomic mass of metal = 42.3 g/mol

\(N_{A}\) = Avogadro's number = \(6.022\times 10^{23}\)

a = edge length of unit cell = \(339.4pm=339.4\times 10^{-10}cm\)    (Conversion factor:  \(1cm=10^{10}pm\)  )

Putting values in above equation, we get:

\(\rho=\frac{4\times 42.3}{6.022\times 10^{23}\times (339.4\times 10^{-10})^3}\\\\\rho=7.19g/cm^3\)

Hence, the density of metal X is \(7.19g/cm^3\)