The rate law for a hypothetical reaction is rate = k [A]2. When the concentration is 0.10 moles/liter, the rate is 2.7 × 10-5 M*s-1. What is the value of k?
Given:
rate = k [A]2
concentration is
0.10 moles/liter
rate is 2.7 × 10-5 Ms-1
Required:
Value of k
Solution:
rate = k [A]2
2.7 × 10-5 Ms-1
= k (0.10 moles/liter)^2
k = 2.7 x 10^-3
liter per mole per second
Answer:The value of rate constant is \(2.7\times 10^{-3} Ls^{-1} mol^{-1}\).
Explanation:
Concentration of [A]=0.10 mol/L
The rate of the reaction = \(2.7\times 10^{-5} M/s\)
Rate constant = k
The given rate law:
\(R=k[A]^2\)
\(2.7\times 10^{-5} M/s=k\times (0.10 mol/L)^2\)
\(k=\frac{2.7\times 10^{-5} mol/L s}{0.10 mol/L\times 0.10 mol/L}=2.7\times 10^{-3} Ls^{-1} mol^{-1}\)
The value of rate constant is \(2.7\times 10^{-3} Ls^{-1} mol^{-1}\).